Chapter Four(第四章) Fundamentals of Kinetics and Mechanism of Electrode Reactions 电极反应动力学与机理1. Introduction2. The mechanism of electron transfer at an electrode3. The theory of electrode reaction4. The relation between current and over potential5. Microscopic interpretation of electron transfer and the Marcus theory
4.1 导言问题:1. 电极电子结构对电化学反应有什么影响?2. 电化学反应速率和电极电势有什么关系? 3. 电子周围环境(溶剂化)对于电极反应影响? Ox + ne = Rd (4.1)在此仅介绍没有化学键形成或断开电极反应,即简单电子转移反应(Outer-Sphere Electron Transfer, 外层电子转移反应)
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