摘要翻译:
对于一系列接近其液汽临界点的纯化合物,仅用四个临界参数$(β{c}){-1}$,$α{c}$,$Z_{c}$,$Y_{c}$,分析了通常的降落伞关联式的主渐近行为,该关联式将表面张力$σ表示为共存液汽间密度差$Rho{L}-Rho{V}$的幂律。...根据工程应用和过程模拟讨论了这些理论估计的主要结果,其中降落伞关联是从密度和毛细管上升测量中估计表面张力的最实用方法之一。
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英文标题:
《Master crossover behavior of parachor correlations for one-component
fluids》
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作者:
Yves Garrabos (ICMCB), Fabien Palencia (ICMCB), Carole Lecoutre-Chabot
(ICMCB), Daniel Broseta (TEFC), Bernard Le Neindre (LIMHP)
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最新提交年份:
2007
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分类信息:
一级分类:Physics 物理学
二级分类:Statistical Mechanics 统计力学
分类描述:Phase transitions, thermodynamics, field theory, non-equilibrium phenomena, renormalization group and scaling, integrable models, turbulence
相变,热力学,场论,非平衡现象,重整化群和标度,可积模型,湍流
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英文摘要:
The master asymptotic behavior of the usual parachor correlations, expressing surface tension $\sigma$ as a power law of the density difference $\rho_{L}-\rho_{V}$ between coexisting liquid and vapor, is analyzed for a series of pure compounds close to their liquid-vapor critical point, using only four critical parameters $(\beta_{c})^{-1}$, $\alpha_{c}$, $Z_{c}$ and $Y_{c}$, for each fluid. ... The main consequences of these theoretical estimations are discussed in the light of engineering applications and process simulations where parachor correlations constitute one of the most practical method for estimating surface tension from density and capillary rise measurements.
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PDF链接:
https://arxiv.org/pdf/707.2001


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